Potentiometric Determination of Hydroxylamine with Lead Tetraacetate

Lithium interference with potentiometric sodium determination.

Potentiometric Determination of Coextraction Constants

1 A theoretical treatment of potentiometric data is applied to calculate coextraction 2 constants (K IA) for three potassium salts from water into a liquid nitrobenzene phase. 3 The experiment involves treating nitrobenzene as a membrane and contacting it with 4 two aqueous solutions of different ion activities. In the presence of either a cation or 5 anion exchanger, the ratio of activities of...

Enantioselective aziridination of alkenes with N-aminophthalimide in the presence of lead tetraacetate-mediated chiral ligand.

[reaction: see text] Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0 degrees C within 15 min. The absolute stereochemistry of the corresponding aziridine derivatives was established by chemical corr...

Thiopental and Phenytoin as Novel Ionophores for Potentiometric Determination of Lead (II) Ions

Two novel polymeric membrane sensors for the analysis of Pb(II) have been developed based on two therapeutic drugs, thiopental (TP) and phenytoin (PT) as two new ionophores and potassium tetrakis(p-chlorophenyl) borate (KTpClPB) as a lipophilic additive, in plasticized PVC membranes. The sensors show a Nernstian response for Pb(II) ions over the wide concentration ranges of 1×10(-2) - 7×10(-6) ...

Simultaneous Determination of Zinc, Cadmium, Lead and Copper in Water by Potentiometric Stripping Analysis

Analysis of zinc (In) cadmium (Cd), lead (Pb) and copper (Cu) in drinking and irrigation waters by potentiometric stripping analysis (PSA) is described. The pH and EC of waters were also determined. The results for zinc and copper were compared with those obtained by atomic absorption spectrophotometry (AAS) which indicated a significantly (P<0.01) strong correlation (r = 0.994 and 0.984 for In...